The First Platinum Formyl, a Member of a Series of Hexanuclear Clusters Exhibiting a Rare Structure

2001 ◽  
Vol 113 (19) ◽  
pp. 3729-3730 ◽  
Author(s):  
Piero Leoni ◽  
Fabio Marchetti ◽  
Lorella Marchetti ◽  
Marco Pasquali ◽  
Silvia Quaglierini
Keyword(s):  
Hexanuclear Clusters

Exploring the Role of Hexanuclear Clusters as Lewis Acidic Sites in Isostructural Metal–Organic Frameworks

2019 ◽  
Vol 31 (11) ◽  
pp. 4166-4172 ◽  
Author(s):  
Jiafei Lyu ◽  
Xuan Zhang ◽  
Peng Li ◽  
Xingjie Wang ◽  
Cassandra T. Buru ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Hexanuclear Clusters ◽  
Lewis Acidic Sites ◽  
Acidic Sites ◽  
Metal Organic

scholarly journals Synthesis and structure of Zr(iv)- and Ce(iv)-based CAU-24 with 1,2,4,5-tetrakis(4-carboxyphenyl)benzene

2016 ◽  
Vol 45 (47) ◽  
pp. 18822-18826 ◽  
Author(s):  
M. Lammert ◽  
H. Reinsch ◽  
C. A. Murray ◽  
M. T. Wharmby ◽  
H. Terraschke ◽  
...  
Keyword(s):  
Hexanuclear Clusters

Eight-fold connection of hexanuclear clusters containing Zr(iv) or Ce(iv) through rigid, rectangular tetracarboxylate ions yields new MOFs with scu topology.

Facile and environmentally friendly synthesis of six heterometallic dumbbell-shaped MII5LnIII4 (M = Co, Ni; Ln = Eu, Gd, Dy) clusters as cryogenic magnetic coolants and molecular magnets

2018 ◽  
Vol 47 (47) ◽  
pp. 16850-16854 ◽  
Author(s):  
Feng Shao ◽  
Jia-Jia Zhuang ◽  
Ming-Guang Chen ◽  
Ning Wang ◽  
Hai-Yan Shi ◽  
...  
Keyword(s):  
Environmentally Friendly ◽  
Molecular Magnets ◽  
Hexanuclear Clusters

The work demonstrates a facile and environmentally friendly synthesis of hexanuclear clusters as cryogenic magnetic coolants and molecular magnets.

On the Structure of Lead(II) Complexes in Aqueous Solutions. III. Hexanuclear Clusters

2002 ◽  
Vol 67 (2) ◽  
pp. 219-227 ◽  
Author(s):  
Martin Breza ◽  
Alena Manová
Keyword(s):  
Quantum Chemistry ◽  
Aqueous Solutions ◽  
Electronic Structures ◽  
Mndo Method ◽  
Experimental Techniques ◽  
Hexanuclear Clusters ◽  
Semiempirical Mndo

Optimum geometries based on experimental structures and corresponding electronic structures of [Pb6(μ3-OH)8]4+ and [Pb6O(μ3-OH)6]4+ clusters as well as of their hydrated [Pb6(μ3-OH)8(H2O)6]4+ and [Pb6O(μ3-OH)6(H2O)6]4+ analogues are investigated using the semiempirical MNDO method of quantum chemistry. Direct Pb-Pb and O-O bonds are vanishing in the systems under study. Small differences in interatomic Pb-Pb and Pb-O distances between these clusters indicate that they cannot be distinguished by recent experimental techniques in solution. Both the mentioned structures are stable and might coexist in solution.

scholarly journals Reprint of: Divalent metal diphenate dipyridylamine coordination polymers: Supramolecular polytypism and a rare 5-connected topology based on arc-like hexanuclear clusters

Polyhedron ◽  
2016 ◽  
Vol 114 ◽  
pp. 459-471 ◽  
Author(s):  
Lucas E. Weingartz ◽  
Joseph H. Nettleman ◽  
Gregory A. Farnum ◽  
Richard J. Staples ◽  
Robert L. LaDuca
Keyword(s):  
Coordination Polymers ◽  
Divalent Metal ◽  
Hexanuclear Clusters

Self-Assembly of Hexanuclear Clusters of 4f and 5f Elements with Cation Specificity

2011 ◽  
Vol 2011 (9) ◽  
pp. 1374-1377 ◽  
Author(s):  
Juan Diwu ◽  
Justin J. Good ◽  
Victoria H. DiStefano ◽  
Thomas E. Albrecht-Schmitt
Keyword(s):  
Self Assembly ◽  
Hexanuclear Clusters
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